Spatial distribution of polycyclic aromatic hydrocarbon contamination in urban soil of China

Abstract

Soil pollution is becoming increasingly prominent and polycyclic aromatic hydrocarbons (PAHs) are key pollutants in urban areas. Understanding the sources of PAH pollution is an effective step toward its control and reduction. The main purpose of this review was to collate the spatial distribution, pollution level, pollution sources, and potential risks of PAHs in urban soils of different regions of China. Relevant data of PAH soil contamination in Chinese provinces and cities were extracted from studies published from 2000 to 2018. The concentrations of total PAHs (Σ16PAHs) ranged from 65.01 to 23603.05 μg/kg for urban soils with a mean of 2801.98 μg/kg. According to the Maliszewska-Kordybach classification criteria, about 47% of the regions of China were heavily contaminated, 23% of the regions were contaminated, and 17% of the regions were weakly contaminated, while only 13% of regions were not contaminated. Based on the results of the total PAHs data from 30 provinces and cities and the results of individual compounds from 27 cities, 18 provinces and cities were classified as “severely” contaminated with a Nemero Comprehensive Index (PI) > 3.0. The results of this review indicate that the main sources of PAH pollution in urban soils of China are coal combustion and automobile exhaust emissions, followed by oil, biomass, and coke tar combustion. This review comprehensively collates the spatial distribution of PAH concentration, their composition, and dominant sources in urban soils of North and South China. Coal and oil combustion contribute more to total PAHs in North China while vehicle emissions and biomass combustion contribute more in South China. This regional difference suggests that PAH pollution in urban soils is a side-effect of a combination of regional development levels and human activities, which differ between North and South China. Risk assessment based on the benzo[a]pyrene toxicity equivalent factor indicates that the concentration of PAHs is low in most parts of China; however, several sensitive areas should receive increased attention. This review aims to provide improved decision-making support toward soil pollution control and monitoring based on the distribution and main pollution sources of PAHs in urban soil of China.