Spatial distribution characteristics and source apportionment of heavy metal(loid)s in park dust in the Mianyang urban area, China.

Abstract

Park dust is a carrier of heavy metal pollutants and could potentially harm the health of urban residents. The concentrations of 10 heavy metal(loid)s (HMs) in park dust from the Mianyang urban area were analysed via X-ray fluorescence spectrometry. Based on ArcGIS spatial analysis, Spearman correlation analysis, spatial autocorrelation analysis, and the positive matrix factorization (PMF) model, the spatial distribution and sources of HMs in park dust were studied. The average contents of Zn, Co, Cu, Cr, Pb, and Ba in park dust were 185.0, 33.7, 38.7, 178.7, 51.0, and 662.1mg/kg, respectively, which are higher than the reference values. The 10 HMs exhibited obvious spatial distribution and local spatial agglomeration patterns. High concentrations of As and Pb were primarily concentrated in the eastern part of the Mianyang urban area. High concentrations of Zn, Cr, and Cu were largely distributed in parks near the Changjiang River and Fujiang River. A high concentration of Co was concentrated in the northern region. The high-value areas of Mn, Ba, V, and Ni occurred far from the city centre and were located in the southwestern region. We found that Pb and As primarily originated from mixed traffic and natural sources; Zn, Cr, and Cu mainly originated from industrial activities; Co largely originated from building sources; and Ba, Ni, Mn, and V were mostly derived from natural sources. Mixed, industrial, building, and natural sources accounted for 24.5%, 24.8%, 24.7%, and 26.0%, respectively, of the HM sources. Co, Cu, Cr, and Zn in the Mianyang urban area were obviously influenced by human activities and should receive close attention.