Abstract
The iodine atoms in 2 P 3/2 and 2 P 1/2 states produced from the laser photodissociation of the reaction products of Al x (or V x ) with CH 3 I are detected by selective 2+1 polarized photoionization one-dimensional time-of-flight mass spectrometric methods and compared with those produced from CH 3 I under the same conditions. The ground-state iodine atoms produced from the products of the reaction of aluminum or vanadium clusters with CH 3 I are not found to be formed along a unique direction. This might suggest that the majority of the iodine atoms detected are produced either from the reaction or else from the photodissociation of metal iodide clusters, which is slower than the cluster rotation, or from an isotropically absorbing oscillator in the metal iodide clusters
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