Spatial Characterization of the Occurrence of Road Salts and Their Environmental Concentrations as Chlorides in Canadian Surface Waters and Benthic Sediments

Abstract

Abstract Increased concern over the contamination of surface waters by road salts and their adverse effects on the freshwater organisms led to the inclusion of “road salts” on the second Priority Substances List (PSL2) under the Canadian Environmental Protection Act The list identifies substances that must be assessed on a priority basis to characterize the nature and extent of the risk they pose to the environment or human health. This paper adds to the collection of several reports which constitute “supporting documentation” for the environmental risk assessment of the priority substance “road salts”. It reviews the physical-chemical properties of inorganic salts commonly used for road maintenance and their fate and transport in surface waters and sediments, together with the environmental concentrations of road salt constituents in the context of watershed geology and other environmental factors governing their concentrations. The paper also provides a spatial map of chloride concentrations as a basis for developing an understanding of a spatially based, ecological risk assessment for surface water systems and relates the spatial risk map to observed concentrations of chlorides. The data suggest that the surface waters most sensitive to road salts impacts are small ponds and streams draining large urbanized areas. Environment Canada is presently considering several alternatives for dealing with road salts.