Spatial and Temporal Variation of PM2.5 and Atmospheric PCDD/Fs in Northern Taiwan during Winter Monsoon and Local Pollution Episodes

Kai Hsien Chi,Yi Na Li,Ngo Tuan Hung

doi:10.4209/aaqr.2017.03.0095

Kai Hsien Chi, Yi Na Li + Show 1 more

Open Access

https://doi.org/10.4209/aaqr.2017.03.0095

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Abstract

ABSTRACTWinter monsoonal air masses traveling from Inner Mongolia to downwind nations can transport cold temperature and air pollutants. This study investigated the effects of the long-range transport (LRT) of air pollutants by northeastern monsoons and local pollution (LP) episodes on atmospheric PM2.5, polychlorinated dibenzo-p-dioxin (PCDD), and polychlorinated dibenzofuran (PCDF) concentrations in northern Taiwan during the winters of 2014 and 2015. Air samples were collected in rural (Rural Site 1 was mountainous; Rural Site 2 was coastal) and urban (Urban Site 1 was urban; Urban Site 2 was suburban) areas in northern Taiwan as well as at a background site (Lulin Mountain) in central Taiwan. Atmospheric PCDD/F concentrations measured at different sites ranged from 11.0 ± 2.70 to 39.7 ± 22.7 fg international toxicity equivalency quantity (I-TEQ) m–3 in 2014 and 7.99 ± 5.58 to 17.5 ± 12.3 fg I-TEQ m–3 in 2015. During LRT and LP, the proportion of PCDFs was higher than that of PCDDs. Rural Site 1 (122 pg I-TEQ g–1) and Urban Site 2 (82.4 pg I-TEQ g–1) had the highest PCDD/F content in PM2.5 during LRT and LP, respectively. The proportion of PCDD increased when neither event occurred. Principal component analysis revealed relationships between the component variance of PCDD/Fs and the sampling site altitude. The results of potential source contribution function (PSCF) suggested that the cold-air masses reaching Taiwan via LRT were most likely arriving from northern China, with pollutants collected along their routes. Wind speed and direction and geographical factors affected the accumulation of air pollutants in the atmosphere during LP.

Highlights

PCDDs and polychlorinated dibenzofuran (PCDF) are airborne persistent organic pollutants that are semi-volatile with low vapor pressure
This study investigated the effects of the long-range transport (LRT) of air pollutants by northeastern monsoons and local pollution (LP) episodes on atmospheric PM2.5, polychlorinated dibenzo-p-dioxin (PCDD), and polychlorinated dibenzofuran (PCDF) concentrations in northern Taiwan during the winters of 2014 and 2015
The results indicated that OCDD was the dominant PCDD/F congener at all three sampling sites during LRT, LP, and the normal period, which corresponded with findings of Coutinho et al (2007) and Zhang et al (2015)

Summary

Introduction

PCDDs and PCDFs are airborne persistent organic pollutants that are semi-volatile with low vapor pressure. The variability of PCDD/Fs at different sampling sites was measured on the basis of the ratio of ΣPCDDs to ΣPCDFs, with a ΣPCDDs/ΣPCDFs ratio of 0.3–0.6 indicating that the pollution is largely due to burning processes (Cappelletti et al, 2016). This explained the ΣPCDDs/ΣPCDFs ratio of 0.37–0.55 at Rural Site 1, Rural Site 2, and Urban Site 1, and 1.95 at Background Site. The prevailing wind in Taiwan blowing eastward in the runup to northeastern monsoons was reported during the winters of 2005 and 2014 (Cheng et al, 2008; Chuang et al, 2016)

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