Spatial and temporal comparisons of dissolved organic matter in river systems of the Three Gorges Reservoir region using fluorescence and UV–Visible spectroscopy

Abstract

Understanding optical characteristics, composition and source of dissolved organic matter (DOM) in rivers of the Three Gorges Reservoir (TGR) region is important for region and global carbon cycle. However, chemical compositions and source of DOM from the tributary to mainstream in the TGR region are not well studied. Consequently, 126 water samples were collected from rivers in different land use region, and these rivers covered the main tributaries of the Yangtze River in the TGR region. The temporal and spatial variations of DOM structure and source identification in different land use region were investigated using UV–visible absorbance and fluorescence spectroscopy. Overall, there were higher ratio of humic acid to fulvic, aromaticity, molecular weight and proportion of colored humic substances in DOM in the wet season than in the dry season. The weaker biologic/microbial and stronger terrestrial sources in DOM were observed in the wet season than in the dry season. DOM comparison in variable land use demonstrated the higher terrestrial sources and weaker biologic/microbial sources in DOM in the forest-affected rivers irrespective of hydrological seasonality, as well as in the wet season irrespective of land use types. DOM in the farmland-affected rivers showed more protein-like signal. We found that monsoonal precipitation, anthropogenic activities and land use were important drivers for the DOM quality variations. These findings will be beneficial to unravel riverine DOM structure and sources in relation to anthropogenic activities and also improve our understanding of DOM biogeochemical cycle in the rivers.