Spatial and Temporal Characterization of PM2.5 Mass Concentrations in California, 1980–2007

Abstract

ABSTRACT Systematic measurement of fine particulate matter (aerodynamic diameter less than 2.5 μm [PM2.5]) mass concentrations began nationally with implementation of the Federal Reference Method (FRM) network in 1998 and 1999. In California, additional monitoring of fine particulate matter (PM) occurred via a dichotomous sampler network and several special studies carried out between 1982 and 2002. The authors evaluate the comparability of FRM and non-FRM measurements of PM2.5 mass concentrations and establish conversion factors to standardize fine mass measurements from different methods to FRM-equivalent concentrations. The authors also identify measurements of PM2.5 mass concentrations that do not agree with FRM or other independent PM2.5 mass measurements. The authors show that PM2.5 mass can be reconstructed to a high degree of accuracy (r 2 > 0.9; mean absolute error ∼2 μg m−3) from PM with an aerodynamic diameter ≤10 μm (PM10) mass and species concentrations when site-specific and season-specific conversion factors are used and a statewide record of fine PM mass concentrations by combining the FRM PM2.5 measurements, non-FRM PM2.5 measurements, and reconstructions of PM2.5 mass concentrations. Trends and spatial variations are evaluated using the integrated data. The rates of change of annual fine PM mass were negative (downward trends) at all 22 urban and 6 nonurban (Interagency Monitoring of Protected Visual Environments [IMPROVE]) monitoring locations having at least 15 yr of data during the period 1980–2007. The trends at the IMPROVE sites ranged from -0.05 to -0.25 μg m−3 yr−1 (median -0.11 μg m−3 yr−1), whereas urban-site trends ranged from -0.13 to -1.29 μg m−3 yr−1 (median -0.59 μg m−3 yr−1). The urban concentrations declined by a factor of 2 over the period of record, and these decreases were qualitatively consistent with changes in emissions of primary PM2.5 and gas-phase precursors of secondary PM. Mean PM2.5 mass concentrations ranged from 3.3 to 7.4 μg m−3 at IMPROVE sites and from 9.3 to 37.1 μg m−3 at urban sites. IMPLICATIONS Mean measured and reconstructed fine particulate matter mass concentrations declined by about a factor of 2 in California over the period 1980 to 2007 and varied by about a factor of 4 among air basins. The integrated data record is of interest for epidemiological studies and for assessments of emission control programs.