Spatial and seasonal variations in trace metals in marine sediments from the Dubai coastal environment.

Abstract

This study was conducted to assess sediment trace metals (Cd, Cr, Cu, Pb, Ni and Zn) contamination using a systematic approach by collecting sediment samples from 8 transects along the Dubai coastline, each 10 km long, and each transect included its nearshore sediment sampling station. Additionally, 10 sediment samples were collected from the Dubai creek and other potential sources of metal pollution. The sediment samples were collected in December and again in August. However, no significant difference in sediment metal concentration was found between the two sampling campaigns. The sediment trace metal concentrations (0.92-1.31mg Cd/kg, 2.82-176.6mg Cr/kg, 2.27-621.67mg Cu/kg, 0.88-23.6mg Pb/kg, 1.92-192.2mg Ni/kg and 9.1-391.05mg Zn/kg) showed considerable variability, except for Cd (1.08 ± 0.06mg/kg, 5.55% variability). Despite this, no significant differences in sediment metal concentrations were found between the sampled transects. However, significant variations in Cr, Cu, Pb and Zn were evident between distances from the shoreline to offshore stations along the Dubai coast, and the nearshore locations presented clear evidence of elevated/maximum sediment metal concentrations. Most of the sediment trace metal concentrations, however, were found well within the sediment quality guidelines (SQGs) for nearshore sediments. Trace metal contamination hotspots, nonetheless, were identified at some nearshore stations as determined by metal level exceedance over the SQGs, background levels and the pollution load index, with limited potential ecological risk. Overall, the findings suggest that sediments in the Dubai coastal environment are mainly influenced by anthropogenic activities in stations located in the proximity of ship maintenance, ports, and industrial areas such as Dry Dock, Jaddaf, Jebel Ali Port, Wharfage, Hamriya and DUBAL.