Spatial and seasonal variability of dissolved metals in a monsoonal estuarine environment

Abstract

Distribution of metals in estuarine surface water reflects their respective sources and abundances in the fresh- and marine- water end-members, mixing processes and ability to take part in various geochemical reactions prevailing in the transitional zone. However, these elements tend to show complex geochemical behaviour, which varies both within and among different estuaries. This makes it difficult to delineate a universal distribution pattern. In this study, the behaviour of multiple dissolved metals (Sr, Ba, Fe, Mn, Mo, V, Co, Cr, Cu, Ni, Zn, U and Pb) have been evaluated in a tropical monsoonal estuary located on the east coast of India during summer (May, 2018), monsoon (September, 2018) and winter (February, 2019) season. Concentration of Sr, Mo, V, Cu and U increases towards the mouth of the estuary, whereas, Ba, Fe, Mn, Pb and Cr concentration shows a declining trend along increasing salinity gradient. All the elements show non-conservative behaviour in the estuary during at least one season within the studied period. Rapid removal of Fe and Mn takes place in the low salinity region, whereas, Mo, V, Pb and U get removed in the low- to mid- salinity zone of the estuary as a result of salinity-induced flocculation. A pronounced mid-estuarine maxima is exhibited by Ni and Zn. Barium shows peak concentrations in the low salinity region. Spatial variation in the occurrence of Ba maxima along the salinity gradient exists between the low and high discharge periods. Seasonally, highest concentration of Sr, Mo, V and U are found in the summer, followed by winter and monsoon. On the other hand, Ba, Fe, Mn, Co, Cr, Cu, Ni and Zn exhibit the highest concentrations during the monsoon period as a result of increased inputs from fluvial sources. The intrusion of seawater during the dry seasons and dilution during monsoon, which shows the highest freshwater discharge, are responsible for the seasonal variations. Thus, this study highlights the variability in distribution of elements as well as the differences in the behaviour of individual elements under contrasting environmental conditions within an estuary.