Spatial Analysis of Heavy Metal Pollution in Road-Deposited Sediments Based on the Traffic Intensity of a Megacity

Abstract

Population growth has led to the intensification of average daily traffic (ADT), highlighting vehicles as one of the major sources of heavy metal (HM) pollution in cities. The objective of this paper is to conduct a spatial analysis of the HM pollution associated with road-deposited sediments (RDSs), based on the ADT observed in the main roads of a Latin American megacity (Bogotá, Colombia). The following risk indices were considered: Geoaccumulation Index (Igeo), Integrated Pollution Index (IPI), Ecological Risk Index (ERI), Comprehensive Potential Ecological Risk Index (CERI), Hazard Index (HI), and Carcinogenic Risk Index (CRI). The findings confirm that a size fraction < 250 μm is the most suitable for studying the risk of HMs in the RDS from the indices considered. The best HMs indicative of the relationship with ADT are Ni, Cu, and Pb. The Pb is the HM of most attention, and Cr gains positions for its toxicity level during the evaluation of ecological, non-carcinogenic, and carcinogenic risks, respectively. Finally, the linear regression models developed between ADT and each of the risk indices considered have a better fit (R2 > 0.910) compared to the linear regression models developed between ADT and HM concentrations (R2 > 0.322).