Spark discharge assisted laser induced breakdown spectroscopy

Abstract

Laser induced breakdown spectroscopy is combined with a spark discharge to operate in a laser triggered spark discharge mode. This spark discharge laser induced breakdown spectroscopy (SD-LIBS) is evaluated for Al and Cu targets in air under atmospheric pressure. Significant enhancement in the measured line intensities and the signal-to-background ratios, which depend on the spark discharge voltage and the laser fluence, is observed in spark discharge laser induced breakdown spectroscopy when compared to laser induced breakdown spectroscopy alone for similar laser conditions. The measured line intensities increase with the applied voltage for both targets, and the ratio of the measured line intensity using spark discharge laser induced breakdown spectroscopy to that using laser induced breakdown spectroscopy is found to increase as the laser fluence is decreased. For Al II 358.56, such intensity enhancement ratio increases from ∼50 to ∼400 as the laser fluence is decreased from 48 to 4 J/cm 2 at an applied voltage of 3.5 kV. Thus, spark discharge laser induced breakdown spectroscopy allows for using laser pulses with relatively low energy to ablate the studied material, causing less ablation, and hence less damage to its surface. Moreover, applying spark discharge laser induced breakdown spectroscopy gives up to 6-fold enhancement in the S / B ratio, compared to those obtained with laser induced breakdown spectroscopy for the investigated spectral emission lines.