Abstract

Charge trapping and de-trapping properties can affect space charge accumulation and electric field distortion behavior in polymers. Dielectric materials may contain different types of traps with different energy distributions, and it is of interest to investigate the charge trapping/de-trapping dynamic processes in dielectric materials containing multiple discrete trap centers. In the present work, we analyze the charge trapping/de-trapping dynamics in materials with two discrete traps in two cases where charges are injected continuously or only for a very short period. The time dependent trapped charge densities are obtained by the integration of parts in the case of continuous charge injection. In the case of instantaneous charge injection, we simplify the charge trapping/de-trapping equations and obtain the analytical solutions of trapped charge densities, quasi-free charge density, and effective carrier mobility. The analytical solutions are in good agreement with the numerical results. Then, the space charge dynamics in dielectric materials with two discrete trapping centers are studied by the bipolar charge transport (BCT) model, consisting of charge injection, charge migration, charge trapping, de-trapping, and recombination processes. The BCT outputs show the time evolution of spatial distributions of space charge densities. Moreover, we also achieve the charge densities at the same position in the sample as a function of time by the BCT model. It is found that the DC poling duration can affect the energy distribution of accumulated space charges. In addition, it is found that the coupling dynamic processes will establish a dynamic equilibrium rather than a thermodynamic equilibrium in the dielectric materials.

Highlights

  • The charge trapping/de-trapping properties determine the formation and accumulation of space charges in dielectric materials [1,2,3,4]

  • When a dielectric material is subjected to a high electric field, free charges can be injected into the bulk of the material from electrodes [5] or can be generated by ionization [6], and they can be captured by trapping centers, which form space charges

  • The charge trapping/de-trapping dynamics of deep traps should be considered during the analysis of transient electrical properties of dielectric materials, such as transient space charge limited current (SCLC), space charge accumulation and dissipation, and transient electroluminescence

Read more

Summary

Introduction

The charge trapping/de-trapping properties determine the formation and accumulation of space charges in dielectric materials [1,2,3,4]. The charge trapping/de-trapping dynamics of deep traps should be considered during the analysis of transient electrical properties of dielectric materials, such as transient SCLC, space charge accumulation and dissipation, and transient electroluminescence. An exponential function was adopted to approximate the energy distribution of traps calculated by the density-functional theory [22] They assumed that the trap centers are filled with free charges from the bottom to the top. From dielectric materials with multiple discrete traps, charge transfer between shallow traps and deep traps can influence the space charge accumulation and dissipation properties. The charges trapped in deep trapped can distort the local electric field and may result in ageing of the dielectric materials

Dynamic Responses of Charge Trapping and De-trapping
Continuous Charge Injection
Continuous Charge Injection dt
Instantaneous Charge Injection
Time-dependent
Steady
Trapped
Bipolar Charge Transport Model
Charge Injection
Charge Reaction Dynamics
Numerical Techniques
Results and Discussion
Space Charge Accumulation Characteristics
Average
Surface
Discussion
Conclusions
Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call