Sources, distribution and transport of atrazine in the St. Lawrence River (Canada)

Abstract

A Lagragangian sampling strategy was chosen in order to evaluate the main sources of atrazine to the St. Lawrence River, Canada. Lagrangian sampling was carried out during six sampling trips, one at every hydrological season except winter from the period of the summer low flow of 1990 to the spring freshet of 1992. Loadings of atrazine are subject to annual variations induced by different climatic and hydrological conditions. Loadings of atrazine are also dependent on season. Results emphasize the persistence of atrazine as it was found in significant amounts at the end of the growing season and in the following spring. Variations in loadings of atrazine along the river as well as the lateral distribution of atrazine concentrations in a downstream direction suggest inputs within the province of Quebec. The Great Lakes and the international corridor of the St. Lawrence River contribute 68% of the loading exported to the estuary, while Quebec tributaries account for 8% of the inputs. The inportance of the unmeasured sources within the river itself (24%) stresses the need for further research on internal processes and contaminant transfer in the aquatic environment.