Source origin and parameters influencing levels of heavy metals in TSP, in an industrial background area of Southern Italy

Abstract

In this paper, we investigate the relationships among atmospheric concentration of trace elements and some meteorological parameters. In particular, the effects of different meteorological conditions on heavy metal levels are interpreted by means of a multivariate statistical approach. The analysed variables were measured during a monitoring survey that started in 1997, and this survey was carried out in order to evaluate the atmospheric concentrations of heavy metals in the industrial area of Tito Scalo (Basilicata Region, Southern Italy). Here we present and analyse the data set collected from 1997 to 1999. The data set includes daily concentrations of total suspended particulates (TSP), daily concentrations of eight metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn) in TSP and daily meteoclimatic data (temperature, rainfall, speed and wind directions). Both the concentration level and the occurrence of peak concentration events are consistent with the characteristics of the study area: abundant small and medium industrial plants in a mountainous and unpolluted zone. Regarding the origin of sources of heavy metals in TSP, the statistical procedure allows us to identify three profiles: SP 1 and SP 2 related to industrial sources and SP 3 related to other sources (natural and/or anthropogenic). In particular, taking into account the effect of different meteorological conditions, we are able to distinguish the contribution of different fractions of the same metal in the detected source profiles.