Source identification and exposure risk management for soil arsenic in urban reclamation areas with high background levels: A case study in a coastal reclamation site from the Pearl River Delta, China

Abstract

Urbanization involving the excavation and reuse of arsenic-bearing geological materials may pose human health risks. We investigated the distribution and sources of soil arsenic at a coastal reclamation site in the Pearl River Delta, China, and proposed risk management strategies. Analysis of 899 soil samples revealed an average of 58.97 mg/kg arsenic, with a maximum of 1450 mg/kg, mainly in fill material obtained from a local island. Integrative analysis combining reclamation history, regional geology, and bedrock mineralogy conclusively identified hydrothermally altered arsenic-bearing sulfide minerals within extensively fractured bedrock as the primary source of arsenic. Physical weathering and anthropogenic rock blasting produced discrete arsenic-rich particles that were directly transported into soils during land reclamation and accumulated to potential hazardous levels. Oral, dermal, and inhalation pathways were identified as primary exposures for future populations. Integrated engineering and institutional controls, coupled with long-term monitoring, were recommended to mitigate risks. The results highlight the importance of identifying specific geogenic and anthropogenic sources that contribute to heavy metal enrichment of soils in reclaimed areas where native bedrock naturally contains elevated level of metals, supporting evidence-based best practices for risk management and future land use.