Source apportionment and influencing factors of surface water pollution through a combination of multiple receptor models and geodetector

Abstract

In line with sustainable development goals (SDGs), precise quantification of water pollution and analysis of environmental interactions are crucial for effectively safeguarding water resources. In this study, Nemerow's pollution index was used to evaluate water quality, three receptor models were used to identify pollution sources, and Geodetector analysis was applied to explore environmental interactions in the North Shangyu Plain, Southeast China. Using 5207 surface water samples from September 2023 with 11 physicochemical parameters, the results showed that surface rivers in the North Shangyu Plain exhibited varying degrees of pollution: slight pollution upstream, moderate pollution in midstream and downstream, and concentrated high pollution in certain areas, with TN, CODCr, and TP as the primary pollutants. Multimethod source apportionment significantly improved the accuracy of pollution source attribution and identified five main sources: domestic sewage (1.42%–3.54%) characterized by NO3-N, phytoplankton source (38.43%–50.05%) indicated by chl and PC, agricultural cultivation (16.1%–17.63%) marked by TP and CODMn, industrial wastewater (17.64%–25.1%) primarily associated with TN, and natural source (10.32%–13.26%) characterized by DO, NH3-N, and CODCr. Influencing factor analysis validated the source identification. Natural factors had minor impacts on water parameters, while pollution control from agricultural activities was suggested to diversify fertilizer types rather than merely reduce quantities. The combined effects of industrial and aquaculture activities intensified pollution from TN, chl, and PC, underscoring the need for targeted management practices. This study showed the objectivity and reliability of using a combined approach of multiple receptor models and Geodetector to evaluate the river water quality status, which helps assist decision-makers in formulating more effective water resource protection strategies.