Abstract

Apportioning sources, assessing flow pathways, and quantifying the interaction between source and transport factors are critical for decreasing nutrient loss from agricultural catchments. In this study, water, nutrient, and tracer (δ18O, electrical conductivity) fluxes were measured over two years from a tile-drained field in Indiana, USA to quantify linkages among water flow pathways, management practices, and nutrient delivery to tile drains. Three-component hydrograph separation showed that tile discharge was, on average, sourced from groundwater (65 ± 31%), shallow soil water (10–20-cm deep; 29 ± 28%), and precipitation (6 ± 8%). Daily nitrate-N (NO3-N) and dissolved reactive phosphorus (DRP) load ranged from 0.0 to 1.8 kg ha−1 and 0–101 g ha−1, respectively, while cumulative loads were 30.7 kg ha−1 and 1,040 g ha−1. Nutrient management practices (fertilizer rate, placement, timing) directly influenced the magnitude of incidental nutrient loss and proportion of load that was derived from a fertilizer source. It was estimated that 52% and 46% of cumulative NO3-N and DRP load, respectively, was incidental loss that occurred within 30 d of fertilizer application. Continuous re-distribution of NO3-N throughout the soil profile following fertilizer application resulted in a broad range of concentration across flow pathways and antecedent conditions. In contrast, dry conditions with tile water sourced from shallow soil water or precipitation resulted in greater, but more variable, DRP concentration compared to wetter conditions when tile water was largely comprised of groundwater. Findings suggest that groundwater table dynamics exerted a strong control over DRP concentration, as similar surface-tile hydrologic connectivity occurred during both dry and wet conditions but produced different water quality outcomes. Groundwater may therefore serve both as a chemical and hydrologic buffer of DRP concentration. Combined measurements of water, nutrient, and tracer fluxes revealed novel insights into processes controlling nutrient delivery to tile drains, with direct applicability for conservation practice implementation and improving process representation in models.

Full Text
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