Abstract
Terpolymer resins have been synthesized by condensation of p-nitrophenol, triethylenetetramine, and formaldehyde in the presence of 2 M NaOH as a catalyst with different molar proportions of monomers. Newly synthesized terpolymers were proved to be selective chelation ion exchangers for metal ions like Fe3+, Cu2+, Ni2+, Co2+, Zn2+, Cd2+, Hg2+, and Pb2+. A batch equilibrium study was carried out over a wide pH range, shaking time, and in media of various ionic strengths of different electrolytes and shows higher selectivity for Hg2+, Cd2+, and Pb2+. Distribution ratios of metal ions were found to be increased by increasing pH of solutions; hence the resins can be used to recover certain metals from waste solutions and removal of iron from boiler water.
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