Abstract
We have established that a typical feature of adsorption processes involving participation of porous ionic crystalline compounds formed by cations of bis-macrocyclic copper(II) complexes is absorption/desorption hysteresis, associated with significant rearrangement of the lattices of the complexes during adsorption/desorption. The compounds studied have high sorption capacity for water and methanol, comparable with that of porous coordination polymers.
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