Abstract

The sorption and desorption characteristics of the major components of gasoline were determined for five media; sandy loam soil, organic top soil, clay soil, peat moss and granular activated carbon (GAC). Emphasis was placed on the sorption of benzene, toluene, ethylbenzene and xylenes (BTEX), the aromatic hydrocarbons contained in gasoline. The results showed that the Freundlich isotherm satisfactorily described the sorption and desorption of dissolved BTEX on the media tested. The organic carbon content of the media was an important factor in both sorption and desorption, with the order of sorption preference being GAC, peat moss, organic top soil, clay soil and sandy loam soil. The soil—water partition coefficient ( K oc) for the BTEX compounds and Total BTEX suggests that the BTEX compounds will migrate quickly through soil, with benzene being the fastest followed by toluene, m-, p- and o-xylenes and ethylbenzene.

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