Abstract
The thermodynamic characteristics of sorption of adamantane and its functional derivatives on graphitized thermal soot (GTS) modified with polyethylene glycol Carbowax 20M were determined by equilibrium gas chromatography. The resulting thermodynamic characteristics were analyzed and compared with the data measured for adamantanes on the surface of nonmodified GTS and polyethylene glycol deposited on an inert substrate. The solid carbon substrate was shown to affect the character of intermolecular interactions in the GTS-modifier system and the retention of framework compounds under the conditions of gas, liquid, and solid-state chromatography.
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