Sorption kinetics and intrapaticulate diffusivity of As(III) bioremediation from aqueous solution, using modified and unmodified coconut fiber

Abstract

The pollution and toxicity problems posed by arsenic in the environment have long beenestablished. Hence, the removal and recovery remedies have been sought, bearing in mind the effi-ciency, cost effectiveness and environmental friendliness of the methods employed. The sorption kinet-ics and intraparticulate diffusivity of As (III) bioremediation from aqueous solution using modified andunmodified coconut fiber was investigated. The amount adsorbed increased as time increased, reach-ing equilibrium at about 60 minutes. The kinetic studies showed that the sorption rates could bedescribed by both pseudo-first order and pseudo-second order process with the later showing a betterfit with a value of rate constant of 1.16 x 10 -4 min -1 for the three adsorbent types. The mechanism ofsorption was found to be particle diffusion controlled. The diffusion and boundary layer effects werealso investigation. Therefore, the results show that coconut fiber, both modified and unmodified is anefficient sorbent for the removal of As (III) from industrial effluents with particle diffusion as the pre-dominant mechanism.