Abstract
Sorption of tracer curium, Cm3+, on SiO2· H2O (silica gel) was investigated under different experimental conditions such as time of equilibration, concentration of Sm3+, pcH, and temperature. Sm3+was used as a carrier for Cm3+ions in this study. From the sorption kinetics data, the diffusion coefficient of Cm3+ion was calculated to be 1.20(±0.05)×10-11m2s-1under particle diffusion-controlled conditions. The sorption rate was determined to be 3.47(±0.19)×10-3s-1at 298 K, pcH 5.25(±0.03) in 0.20 M (NaClO4). The sorption data were fitted in Freundlich, Langmuir and Dubinin–Radushkevich (D–R) isotherms. A synergistic enhancement in the sorption of Cm3+(Sm3+)-ligand (e.g., CO32-, F-, H2PO4-and C2O42-) complexes on silica gel was observed. The presence of these anions increase the sorption of Cm3+(Sm3+) in the following order: CO32-< F-< C2O42-< H2PO4-. Temperature variation experiments gave enhanced sorption with increased temperature for Cm3+indicating an endothermic enthalpy.
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