Abstract
Abstract The ZnII‐CoII organic framework [Me2NH2][Zn2Co(μ3‐OH)(BTC)2(H2O)]·2H2O (FJI‐6) (H3BTC = 1, 3,5‐benzenetricarboxylic acid and DMA = N.N′‐dimethyl acetamide), was synthesized and structurally characterized. FJI‐6 shows a three‐dimensional heterometallic microporous framework with coexisting octahedral cages and one‐dimensional channels assembled by Zn2Co(μ3‐OH)(CO2)6 secondary building units. In addition, the sorption behavior and magnetic properties of FJI‐6 were investigated.
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