Abstract

This paper deals with the sonochemical water treatment of polycyclic aromatic sulfur hydrocarbons (PASHs), one of the most common impurities found in waste water coming from petroleum industry. The best fit of the experimental data appears to be the kinetic parameters determined using the Michaelis-Mentonmodel in the concentrations range of the study. For the initial increase in the degradation rates, it is simply considered that the more the bulk concentration increases, the more the concentration in the interfacial region increases. This will be explained by Michaelis-Menton kinetics. The influence of organic compounds in the water matrix as a mixture with Benzothiophene (BT) was also evaluated. The results indicated that BT degradation is unaffected by the presence of bisphenol A (BPA). Finally, the results indicated that ultrasonic action is involved in oxidation rather than pyrolitic processing in the BT sonochemical degradation.

Highlights

  • Polycyclic aromatic sulfur hydrocarbons (PASHs) are compounds found as impurities in crude oil.polycyclic aromatic sulfur hydrocarbons (PASHs) can be found in waste water from the petroleum industry

  • PASHs can be found in waste water from the petroleum industry

  • C effect that was used for the study was prepared upon BT dissolution (90 mg/L)

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Summary

Introduction

Polycyclic aromatic sulfur hydrocarbons (PASHs) are compounds found as impurities in crude oil. PASHs can be found in waste water from the petroleum industry. These sulfur compounds accumulate in sediments and animal tissues, exhibiting toxic and mutagenic properties [1,2]. Classical treatment used in waste water and drinking water plants cannot always supply water that meets current and future regulation requirements. Since the early 1970s, processes named Advanced Oxidative Processes (AOPs) have been under development to improve the efficiency of water treatment [3]. AOPs are based on the production and the use of the hydroxyl radical ◦ OH

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