Sono-catalytic syngas production by low-temperature biomass gasification

Abstract

Syngas holds a crucial role in diverse industrial applications, including chemical synthesis and power generation. It has been traditionally generated through high-temperature processes, such as steam reforming or biomass gasification, demanding temperatures of up to 1200 °C, which results in substantial energy consumption. Consequently, there is a growing interest in exploring alternative, low-temperature biomass gasification processes. This paper introduces an innovative method for syngas production through sono-catalytic biomass conversion at significantly lower temperatures. The approach employs a sonochemical reactor that concentrates acoustic waves to activate inertial cavitation. Furfural, a biomass-derived platform chemical, was chosen as the primary chemical for the study, showcasing the potential of sonochemical syngas production. The reaction converted furfural into various gas products, particularly a mixture of hydrogen and carbon monoxide, with the chemical reaction hypothesized to be triggered by pyrolysis during bubble collapse hot spots. The incorporation of heterogeneous metal foams into the system further enhanced furfural conversion rates. This improvement was attributed to the preferential nucleation of cavitation bubbles on the porous metal foam surface, bringing the hot spots into proximity with furfural molecules. This application of sonochemistry in furfural pyrolysis at low temperatures holds promise for a more economical approach to biomass valorization.