Abstract
Solid complexes of plutonylion with benzoyl (PMBP), acetyl (PMAP) and trifluoroacetyl (PMTFP) derivatives of 1-phenyl-3-methylpyrazol-5-one and various oxo donors such as dihexyl sulfoxide (DHSO), dioctyl sulfoxide (DOSO), dibutyl hexanamide (DBHA), dibutyl octanamide (DBOA) and dibutyl decanamide (DBDA) have been synthesized and characterized. Analytical data establish that sulfoxides form 1∶1 adducts and have the stoichiometry PuO2·X2·Y (X=PMBP, PMAP and PMTFP) and Y=DHSO and DOSO while amides form 1∶2 adducts of the type PuO2X2·2A where A=DBHA, DBOA and DBDA. The I. R. spectra of sulfoxide and amide complexes indicate that the ligands are O-bonded. Spectrophotometric investigations of the benzene solution of these complexes indicate a bathochromic shift of the 831 nm peak to 848–853 nm region, which confirms the retention of PuO 2 2+ moiety in these synergistic adducts.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Radioanalytical and Nuclear Chemistry Articles
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
