Abstract

Preparation of monosubstituted thiourea complexes of molybdenum carbonyl [Mo(CO) 5L] both by thermal and UV irradiation methods have been described. The ligands (L) used were N,N′-dimethylthiourea (DMTU), N,N′-diphenylthiourea (DPTU), tetramethylthiourea (TMTU) and tetraethylthiourea (TETU). The complexes [Mo(CO) 5(L)] were characterised by NMR, IR, UV-visible and elemental analyses.

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