Abstract
Abstract A new potential tridentate tripodal ligand, bis (diphenylselenophosphinyl)diphenylthiophosphinylmethanide, and its neutral protonated parent have been synthesized. The stable conformations of HTrisSSe2 and its trichalcogen analogues can be determined by variable temperature 31p NMR spectroscopy because of significant differences in chemical shifts for a particular chalcogenophosphinyl group in different stereochemical orientations within the sterically hindered molecules.
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