Abstract

Several reactions of potassium perfluoro-t-butoxide with strong oxidizing agents have been studied. The new compounds (CF 3) 3COOSO 2F and (CF 3) 3CONO 2 have been prepared by reactions with peroxydisulfuryl difluoride and nitryl fluoride, and their properties are reported. Evidence is also presented for the formation of the novel peroxy salt KOOCF 3 in the reaction with bis(fluoroxy)difluoromethane. A mechanism for the reaction of —OF compounds with KOC(CF 3) 3 is proposed.

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