Abstract
AbstractA series of gem‐dibromocyclopropanes were treated with various metal complexes. Among the metal complexes, Ru(CO)2(PPh3)3, Ru(CO)3(PPh3)2, and Mo(CO)6 were able to remove a bromine atom from 1,1‐dibromo‐2‐phenylcyclopropanes (1) to yield a series of corresponding of 1‐bromo‐2‐phenylcyclopropanes (2). Upon the treatment of 1 with Cr(CO)6 in DMSO, a series of allenes were obtained in good yields. The correlation between the rate of formation of allenes and the substituents on the benzene gives a negative coefficient which suggests the dibromocyclopropanes possesses as an electrophile toward to Cr(CO)6. In the presence of Cr(CO)6, gem‐dibromobicyclo[n,1,0]alkanes (4) in DMF or DMSO solution underwent the cleavage of carbon‐bromine bond followed by ring‐expansion and coupling reaction to form bicycloalkenes 7.
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