Abstract
1. The amides of dialkylphosphoric acids are formed when the dichloromethyleneamidophosphates are treated with water in the presence of triethylamine; isocyanatophosphoric acid esters are formed when the same dichlorides are treated with formamide. 2. The corresponding N-phosphorylated iminocarbamic acids are apparently formed as intermediate products when formamide, methylformamide or water is reacted with the acid chlorides of the N-phosphorylated iminocarbamic acids, which then rearrange to the N-phosphorylated ureas.
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