Abstract

1. The boron atom is capable of coordinating four perchlorato groups with the formation of the complex anion [B(ClO4)4]−. 2. The properties of cesium perchloratoborate were studied. The low heat stability of Cs[B(ClO4)4] is explained by the substantial deviation in the symmetry of the ClO4 groups from tetrahedral and a weakening of the Cl-O(B) bonds.

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