Some physical properties of (Bi 2O 3) x(BaO) 0.5− x(B 2O 3) 0.5 glasses

Abstract

A series of (Bi 2O 3) x (BaO) 0.5− x (B 2O 3) 0.5 glasses were prepared from pure oxides. The glass transition temperature little decreased from 450 to 419 °C with the increase in x from 0.2 to 0.4. The coefficient of thermal expansion was found at around 10 ± 1 ppm °C −1, practically independent on x. The structural make-up of the glasses was suggested to be formed by structural groups of BaBi 2B 4O 10 and BiBO 3 for 0.25 < x ≤ 0.5, BaBi 2B 4O 10 and BaB 2O 4 for x < 0.25 and by BaBi 2B 4O 10 for x = 0.25. The optical band gap was determined in the region 3.35–3.54 eV and the coefficient of the temperature dependence of the optical gap for the temperatures between 30 and 250 °C was found nearly constant at around (5.5 ± 0.5) × 10 −4 eV K −1. The non-linear refractive index of the studied glasses was estimated from the optical gap values at around 0.9 × 10 −11 esu.