Abstract
Three new Schiff base adducts, [SnMe2Cl2(H2cdnaphen)] (1), [SnPh2Cl2(H2cdnaphen)2].C6H6 (2) and [SnBu2Cl2(H2cdnaphen)2] (3) were synthesized by the reaction of SnR2Cl2 (R = Me, Bu and Ph) with a Schiff base ligand, Methyl 2-[2-(2-hydroxynaphthaldimino)ethylamino]-1-cyclopentene-1-dithiocarboxylate (H2cdnaphen). The new products were characterized by elemental analysis, IR, 1H NMR and 119Sn NMR spectroscopies. Spectroscopic data suggest that H2cdnaphen exists predominately in keto-amine tautomeric form and in all complexes acts as a monodentate neutral ligand coordinating with the metal through oxygen atom, while the sulfur atom and imine nitrogen are not involved in coordination with the tin. Thermal decomposition of the complexes was studied through thermogravimetry and the thermodynamic activation parameters were determined by the Coats-Redfern method.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
