Abstract
Abstract New cyano and isonitrile complexes of molybdenocene, [MoCp2(CN)X] (X = CN, H, Cl), [MoCp2(CNCH3)X]I (X = H, I, CH3), [MoCp2(CNCH3)2]I2 and [MoCp2(CNCH3)], were prepared and characterized. The molybdenocene adduct, [MoCp2(CNCH3)], was prepared by reduction of [MoCp2Cl2] with Na/Hg or from [MoCp2(CNCH3)H]I with NaH. The other complexes were obtained from reaction of [MoCp2IX] (X = H, I) with the appropriate ligand.
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