Abstract
In order to demonstrate the versatility of pulse radiolysis, three examples from various fields of physical chemistry are given: (a) the formation and disappearance of a short-lived thallium–silver cluster is described, (b) as a new method to determine the “salting-out” effect, the concentration of nitrous oxide in aqueous solutions of various sodium chloride content is measured kinetically by monitoring the decay of hydrated electrons, and, (c) the rate constants for the reactions of hydroxyl radicals and hydrogen atoms with a series of aliphatic alcohols are determined from the increase in optical absorption in the UV region typical for alcohol radicals.
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