Abstract
Abstract Aniline was obtained in place of the desired N(2.3.4.5.6‐pentahydroxyhexyl)‐N‐(phenyl)‐amine on reduction of glucose‐anilide with aluminium amalgam or with Pd and hydrogen. Reduction of glucosoxime with 3% sodium amalgam afforded glucamine, which could then be combined with 1‐choro‐2.4‐dinitrobenzene, picryl chloride, 1‐chloro‐2.4‐dinitronaphthalene and 1.3‐dichloro‐4.6‐dinitro‐benzene to give N(2.4‐dinitrophenyl)‐glucamine, N(2.4.6‐trinitrophenyl)‐glucamine, N(2.4‐dinitronaphthyl)‐glucamine and N(3‐chloro‐4.6‐dinitro‐phenyl)‐glucamine. Galactosoxime can also be reduced with 3% sodium amalgam to give galactamine, which can be condensed with the compounds given in (2) to give N(2.4‐dinitrophenyl)‐galactamine, N(2.4.6‐trinitrophenyl)‐galactamine, N(2.4‐dinitronaphthyl)‐galactamine and N(3‐chloro‐4.6‐dinitrophenyl)‐galactamine.
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