Abstract
A new 3D heterometallic coordination polymer (HCP), which formulated as {[Ca(H2O)2][LCo]·DMSO·2H2O}n (1) (DMSO = dimethyl sulfoxide), has been solvothermally synthesized from metalloligand LCo = [Co(2,4-pydca)2]2– (2,4-pydca = pyridine-2,4-dicarboxylate) and alkaline-earth ion CaII. HCP 1 has been well characterized by Fourier-transform infrared spectroscopy, elemental analysis and single-crystal X-ray diffraction analysis. The crystallographic analysis indicates that HCP 1 crystallizes in the monoclinic system with space group of C2 and possesses the 3D framework structure, which is constructed from metalloligands LCo connecting with CaII ions via the carboxyl groups. The 3D framework of HCP 1 can be defined as (4,4,4)-connected 3-nodal topology with the point symbol of {42·84}{42·84}{42·84}. Thermogravimetric analysis exhibits that the skeleton of HCP 1 collapses after 375 °C. Magnetic susceptibility study reveals the presence of antiferromagnetic interaction between the spin centers. The solid-state luminescence property of HCP 1 has also been investigated.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
