Abstract

A novel 3D tri-n-butyltin complex [(n-Bu3Sn)2(C2H2N4SCO2)]n (1) has been solvothermally synthesized and structurally characterized by elemental analysis, FT-IR, NMR (1H, 13C, and 119Sn) spectra and X-ray crystallography. X-ray data of complex 1 reveals that it is a 3D tri-n-butyltin coordination polymer with a metal-organic framework (MOF) structure , significant N → Sn interactions plays an important role in the construction of this structure.

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