Abstract
Solid compounds of composition SnCl 2(CH 2BrCOO) 2, Ti(CH 2BrCOO) 4, Zr(CH 2BrCOO) 4, Th(CH 2BrCOO) 4, Si 2O(CH 2BrCOO) 6 have been isolated when the respective tetrachlorides are refluxed with excess of monobromoacetic acid. Zirconylchloride forms the compound ZrO(CH 2BrCOO) 2. CH 2BrCOOH in a similar manner. These compounds have been characterized by their elemental analysis, molar conductance and by infrared studies, NMR and FAB mass spectrometry. In solution, the bromoacetate groups readily lost. Their Lewis acid character was established by isolating and characterizing their adducts with organic tertiary bases. Antimony pentachloride, aluminium trichloride and ferric chloride form compounds of composition SbCl 2(CH 2BrCOO) 3, Al(CH 2BrCOO) 3, FeCl(CH 2BrCOO) 2 and Fe(CH 2BrCOO) 3 when refluxed with excess of the solvent and these have been characterized by infrared studies.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
