Abstract

AbstractThe stereochemistry and mechanism of solvolysis of optically active tert‐butylphenylphosphinothioic‐O‐trifluoromethanesulphonate (1) in solvents of different ionizing power were studied. It was found that in solvents of high ionizing power and low nucleophilicity 1 ionizes with the formation of a phosphathiacylium cation (2) as the reaction intermediate. Product resulting from the reaction of 2 with anisole was isolated and characterized.

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