Abstract
Solvolyses of monosubstituted benzhydryl bromides gave excellent linear correlations of logk with σ + constants, and not with Y(BnBr) or Y(Br). Correlation analyses against corresponding logk of α-tert-butyl-(2-naphthyl) methyl bromide provided evidence for the importance of different extent of solvation in delocalized transition state and for nucleophilic solvent intervention in the solvolysis of benzhydryl systems.
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