Abstract
Abstract The chemical shifts of methyl protons of a number of bicyclo[3.1.1]heptanols and their acetates were measured on carbon tetrachloride and benzene in order to examine the correlation between the benzene-induced shifts and the spatial arrangements of the functional groups concerned. Thus, the shifts induced by benzene were found to be useful in establishing both the location and the stereochemistry of methyl protons situated in the vicinity of the hydroxyl or the acetoxyl function in a pinane skeleton.
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