Abstract

During biomass conversion, solvent types often play an important role in determining product selectivity and reaction mechanisms. Nevertheless, solvent function remains poorly understood. Herein, Ni/β40 was prepared by a slightly modified deposition-precipitation method and used for the catalytic hydroconversion (CHC) of benzyloxybenzene (BOB) to dicyclohexylmethane (DCHM) or toluene and phenol mediated by solvent types. The results show that solvent types, atmospheres, and Ni20/β40 synergistically control product regulation. In n-hexane (H), DCHM was first produced with the selectivity of 94.5% under the optimum conditions (180 °C, 2 MPa H2, and 4 h). In isopropanol (IP), toluene and phenol were unique products under the optimal conditions (180 °C, 0.5 MPa H2, and 4 h). The characterizations of Ni20/β40 and variation of product distributions from the CHC of BOB demonstrates that BOB conversion to DCHM in H via the >CH-O- bond cleavage induced by H+ addition, benzylium addition to ortho and para positions of phenol, H…H transfer to the resulting 2-benzylphenol and 4-benzylphenol, dehydroxylation of 2-benzylcyclohexanol and 4-benzylcyclohexanol produced, together with benzene rings hydrogenation. By contrast, conversion of BOB to toluene and phenol in IP only depends on the cleavage of >CH-O- bond induced by H+ addition. Furthermore, Ni20/β40 exhibites splendid reusability.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.