Solvent-Induced Degradation of Electrochemically Exfoliated Vanadium Selenide Visualized by Electron Microscopy.

Abstract

Recently discovered two-dimensional ferromagnetic materials (2DFMs) have rapidly gained much interest in the fields of spintronics and computing, where they may prove powerful tools for miniaturizing devices such as magnetic tunnel junctions and spin-transfer torque memory bits. In addition, heterojunctions and twisted bilayer stacks of such materials may yield exotic spin textures. However, preparation of such devices is complicated by the air sensitivity of many 2DFMs. Here, we report details on the preparation of few-to-monolayer flakes of vanadium selenide (VSe2) using electrochemical exfoliation in propylene carbonate. We also present a detailed study of the effects of air on the structure and magnetic properties of bare and passivated VSe2 after different concentrations of surface passivation treatment. We characterized the microstructure of holes in the VSe2 flakes and the formation of new compounds arising from air exposure, solvent exposure during the exfoliating process, and deliberate electron beam irradiation (sculpting). We sculpt VSe2 flakes while retaining the 1T-VSe2 lattice structure, opening the door for top-down patterned high-resolution 2DFM nanostructures. Additionally, investigation of the magnetic response of nanosheets using magnetic force microscopy (MFM) showed that the oxidation-induced damage only affects the surface fields locally and does not quench large-scale magnetic signal. The findings of this study pave the way toward practical incorporation of 2D ferromagnetic materials in nanoelectronics.