Abstract
A new hydrophobicity parameter for water-organic solvent mixtures is proposed. This hydrophobicity concept ( H) includes the thermodynamic activity of solvent and solvent polarity parameter from Dimroth-Reichardt transition energy [ E T(30)]. Solvent hydrophobicity ( H) was a useful tool for the prediction of the threshold concentration C 50 for biocatalytic oxidation of five hydrophobic substrates with lignin peroxidase and cytochrome c, in aqueous solutions of water-miscible organic solvents.
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