Abstract
The direct and solvent-free synthesis of yttrium borohydride was achieved by reactive ball milling of yttrium hydride in diborane/hydrogen atmosphere. The product contains only the solid elemental hydride as remaining contaminant. Yields above 75% were obtained. The product crystallizes in the cubic α phase and releases hydrogen above 460 K. The decomposition was measured by in situ X-ray diffraction and the hydrogen release was monitored gravimetrically in conjunction with infrared gas analysis. No diborane was detected during the decomposition. © 2011 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
