Abstract
Neat biofuel in HD: Linalool, a linear terpene alcohol, can be selectively converted by ruthenium metathesis catalysts under solvent-free conditions to 1-methyl-cyclopent-2-enol and isobutylene in quantitative yield. Dehydration of the alcohol under mild conditions followed by low-temperature thermal dimerization yields methylcyclopentadiene dimer, which can be readily converted into a high-density fuel.
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