Solvent Extraction of Zinc(II) and Manganese(II) with 5,10,15,20-Tetraphenyl -21H,23H-Porphine (TPP) through The Metal Exchange Reaction of LEAD(II)-TPP (Dept.M)

Seham Nagib

doi:10.21608/bfemu.2020.128551

Solvent Extraction of Zinc(II) and Manganese(II) with 5,10,15,20-Tetraphenyl -21H,23H-Porphine (TPP) through The Metal Exchange Reaction of LEAD(II)-TPP (Dept.M)

Seham Nagib

Open Access

https://doi.org/10.21608/bfemu.2020.128551

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Journal: MEJ. Mansoura Engineering Journal	Publication Date: Dec 8, 2020
License type: cc-by

#Solvent Extraction Of Zinc #Hydrophobic Porphyrin + Show 8 more

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Abstract

An investigation was carried out on the extraction of aqueous Zn(II) and Mn(π) with a hydrophobic porphyrin (5,10,15,20-tetraphenyl-21H,23H porphine, TPP) through a metal exchange reaction of Pb(π)-TPP. The distribution ratios (D) of these metals were found to be independent of the Pb(π) concentration in the aqueous phase. Pb(π) in the aqueous phase acted as a catalyst which promoted the metal-TPP complexation.

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